Celta Vigo swept to a shock 4-1 victory over Barcelona, while Real Madrid went top of the Spanish league with a 2-1 win over Athletic Bilbao on Wednesday.
Two goals by Iago Aspas helped Celta to a convincing victory over Barcelona and second place in the table, level on 13 points with Madrid after five rounds.
Karim Benzema scored twice for Madrid, opening the scoring in the 19th minute after intercepting a terrible back-pass by Mikel San Jose and racing forward to score. Sabin Merino equalized with a header, the first goal Madrid goalkeeper Keylor Navas has conceded this season, but Benzema scored his fifth goal so far this season after latching onto Isco pass. Elsewhere, Rayo Vallecano beat Sporting Gijon 2-1 and levante drew 2-2 with Eibar.